宋剑斌, 袁全平, 黄 彪, 侯俊峰, 杨文斌. 适宜共混速度改善低密度聚乙烯/竹粉复合材料力学与流变性能[J]. 农业工程学报, 2015, 31(13): 309-314. DOI: 10.11975/j.issn.1002-6819.2015.13.043
    引用本文: 宋剑斌, 袁全平, 黄 彪, 侯俊峰, 杨文斌. 适宜共混速度改善低密度聚乙烯/竹粉复合材料力学与流变性能[J]. 农业工程学报, 2015, 31(13): 309-314. DOI: 10.11975/j.issn.1002-6819.2015.13.043
    Song Jianbin, Yuan Quanping, Huang Biao, Hou Junfeng, Yang Wenbin. Proper blending rate improving mechanical and rheological properties of low density polyethylene/bamboo composites[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2015, 31(13): 309-314. DOI: 10.11975/j.issn.1002-6819.2015.13.043
    Citation: Song Jianbin, Yuan Quanping, Huang Biao, Hou Junfeng, Yang Wenbin. Proper blending rate improving mechanical and rheological properties of low density polyethylene/bamboo composites[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2015, 31(13): 309-314. DOI: 10.11975/j.issn.1002-6819.2015.13.043

    适宜共混速度改善低密度聚乙烯/竹粉复合材料力学与流变性能

    Proper blending rate improving mechanical and rheological properties of low density polyethylene/bamboo composites

    • 摘要: 该文主要研究共混速度对(low density polyethylene,LDPE)/竹粉木塑复合材料、流变性能和吸水率的影响。采用熔融共混方法制备LDPE/竹粉复合材料,通过旋转流变仪、扫描电镜(scanning electron microscope,SEM)和材料试验机等详细研究了共混速度(40,75和100 r/min)对LDPE/竹粉复合材料的复合材料动态力学性能、形态、吸水率和力学性能的影响。在LDPE/竹粉复合材料,LDPE、增容剂马来酸酐接枝聚乙烯(maleic anhydride grafted polyethylene, MAPE)和竹粉的质量比控制在65∶5∶30。共混温度和时间分别设定为170℃和10 min。结果表明,添加竹粉可有效增强LDPE的力学性能。LDPE/竹粉复合材料的拉伸强度和弯曲强度随着共混速度的增加而呈现下降趋势,但是与纯LDPE相比,LDPE/竹粉复合材料(40 r/min)的拉伸强度和弯曲强度分别增加了28%和115%;弯曲模量从48.45 MPa降低到40.75 MPa。与LDPE相比,LDPE/竹粉复合材料(40 r/min)的弯曲模量最高增加了238%;缺口冲击强度则从12.8 kJ/m2提高到18.27 kJ/m2,但仍低于纯LDPE。在相同频率下(1.0 Hz),随着共混速度的增加,LDPE/竹粉复合材料的储能模量和复数黏度也逐渐下降, 加工性能得到了改善; 同时复合材料的吸水率也从0.89%(40 r/min)下降至0.59%(100 r/min)。SEM结果表明,竹粉能均匀分布在LDPE中,提高共混速度使得竹粉表面被大量树脂覆盖,改善了界面性能,使得材料断裂面产生大量的塑性形变,提高了材料韧性和冲击强度。试验结果证实共混速度为100 r/min时,LDPE/竹粉复合材料具有较好的冲击强度和较低的吸水率,这为木塑复合材料力学性能和吸水率的改善提供有意借鉴。

       

      Abstract: Abstract: In fact, the ultimate properties of wood-plastics composites (WPCs) not only rely on the structure, composition and morphology, but also depend on the processing conditions, such as processing temperature, pressure (blending rate ) and time. Due to the degradation of bamboo powder under high processing temperature or long processing time, this paper studied mainly the effects of blending rate on the mechanical and rheological properties of low density polyethylene (LDPE)/bamboo powder composites, which were fabricated by the melt compounding method with the compounding temperature of 170 ℃and 10 min, by using the rotational rheometer, material testing machine and scanning electron microscope (SEM). The maleic anhydride grafted polyethylene (MAPE) was selected as the compatibilizer for LDPE and bamboo powder. The mass proportion of LDPE, MAPE and bamboo powder was set to 65:5:30. The mechanical properties, water absorption and morphology of LDPE/bamboo composites were investigated in detail by changing the blending rate (40, 75 and 100 r/min). Before experiments, all the materials were dried in vacuum oven at 70 ℃for 24 h. The addition of bamboo powder improved the tensile strength and flexural strength of LDPE, which were increased by 28% and 115% respectively compared to neat LDPE, but reduced the impact strength of LDPE. The tensile strength and flexural strength of the LDPE/bamboo composites decreased as the rotation rate increased from 40 to 100 r/min. The flexural modulus of LDPE/bamboo composites decreased from 48.45 to 40.75 MPa as blending rate increased from 40 to 100 r/min, and the highest flexural modulus increased by 238% compared to neat LDPE (14.35 MPa); however, the notched impact strength of LDPE/bamboo composites increased from 12.8 (40 r/min) to 18.27 kJ/m2 (100 r/min), lower than that of neat LDPE (29.19 kJ/m2). For rheological experiments, the LDPE/bamboo composites exhibited shearing thinning behaviors, and at the same frequency, the complex viscosity of LDPE/bamboo composites decreased as blending rate increased, indicative of the improvement in processing performance; the storage modulus of LDPE/bamboo composites also reduced as blending rate increased, indicating the rigidness reduction, and this result was consistent with the results from mechanical properties. Also, the water absorption of LDPE/bamboo composites decreased from 0.89% (40 r/min) to 0.59 % (100 r/min). The reason was that the high blending rate caused the LDPE and bamboo powder to compound more evenly and the interfacial performance between LDPE and bamboo power was improved. The SEM results showed that at low blending rate (40 r/min), the bamboo powder surface was only coated with a thin layer of resin, and the interface between LDPE and bamboo powder was very clear, indicative of poor interfacial properties, and no plastic deformation was observed; at high rotation rate (100 r/min), bamboo powder was coated with a thick layer of polymer resin, exhibiting good interface performance with LDPE, and what's more, the big plastic deformation was observed in matrix, suggesting LDPE/bamboo composite (100 r/min) exhibited a good toughness. The above results confirmed that elevating blending rate could improve the toughness and reduce the water absorption of LDPE/bamboo composites, and in our experiments, the LDPE/bamboo composites, produced by blending rate (100 r/min), exhibited the better impact strength and water absorption.

       

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