不同添加剂对厨余垃圾堆肥NH3和H2S排放的影响

    Effect of additives on NH3 and H2S emissions during kitchen waste composting

    • 摘要: 近年来中国的城镇化率越来越高,生活垃圾产量也随之剧增,作为生活垃圾中的宝贵资源,厨余垃圾的堆肥化处理得到广泛关注。为了减少厨余垃圾在堆肥化利用过程中的臭气排放,该研究以纯厨余垃圾堆肥作为CK1,以添加15%玉米秸秆的厨余垃圾堆肥CK2,并在CK2的基础上选择吸附剂(活性炭+沸石,膨润土)、表面活性剂(β-环糊精,鼠李糖脂)、堆肥菌剂(城市固体垃圾专用菌(SUKAZYE-MW),酵母菌)这3类材料作为添加剂,每种添加剂设置3个不同的添加量,以NH3和H2S作为监测物质,在实验室内使用广口瓶进行模拟堆肥,研究了不同添加量的各种添加剂对厨余垃圾堆肥过程中臭气减排效果的影响。研究结果表明,添加秸秆后可以减少NH3排放7%~23%,减少H2S排放38%~50%;在CK2的基础上添加2%的活性炭+沸石氨气控制效果最佳,与对照处理相比可分别使NH3的排放量再减少84%和79%,但2种吸附材料对H2S减排效果不佳;2种表面活性剂对NH3的减排效果均不明显,但添加1%的β-环糊精可以在CK2的基础上使H2S排放减少35%;与CK2相比添加0.4%的城市固体垃圾专用菌可以使NH3减排72%、H2S减排33%。该研究结果为厨余垃圾堆肥过程中臭气减排材料的选择提供了参考。

       

      Abstract: Abstract: In recent years, the urbanization rate in China is steadily increasing, and the production of the municipal solid waste is also increasing. As the precious resource among the municipal solid waste, the kitchen waste composting has received widespread attention. In order to reduce the odor emission in the composting process of kitchen waste, this study investigated the effect of additives on the odor emissions (ammonia and hydrogen sulfide) of kitchen waste composting. Two control treatments were set in the study, the CK1 used pure kitchen waste to compost, and the mixture of kitchen waste and 15% (wet weight) of cornstalks was CK2. On the basis of CK2, 3 types of additives were used to compost kitchen waste, and they were adsorbent (activated carbon + zeolite, bentonite), surfactant (β-cyclodextrin, rhamnolipid) and composting inoculants (bacteria agent for municipal solid waste (SUKAZYE), saccharomycetes). Each additive had 3 kinds of adding amounts, and the monitoring substance was ammonia and hydrogen sulfide. The effects of different additives with different adding amounts on the emission of ammonia and hydrogen sulfide from the kitchen waste composting were investigated under laboratory simulation conditions, and the compost was finished in the jars (the volume was 1 L) under aerobic conditions. The results showed that compared with the kitchen waste compost, adding cornstalks could reduce the ammonia emission by 7%-23%, and reduce the hydrogen sulfide emission by 38%-50% during the composting process. Based on the treatment CK2, adding 2% of activated carbon + zeolite showed the best control effect of ammonia emission, and it could reduce the ammonia emission by 84% compared with the CK1 and by 79% compared with the CK2. But when it came to the control effect of hydrogen sulfide, neither activated carbon + zeolite nor bentonite showed a good performance. The results of the 2 kinds of surfactant showed that β-cyclodextrin and rhamnolipid had little effect on the emissions of ammonia, but adding 1% of the β-cyclodextrin could reduce the hydrogen sulfide emission by 35% compared with the treatment CK2. The results of the 2 kinds of composting inoculants showed that adding 0.4% of bacteria agent for municipal solid waste (SUKAZYE) could reduce the ammonia emissions by 72% and reduce the hydrogen sulfide emission by 33% compared with the treatment CK2. In summary, the addition of corn straw can effectively reduce the hydrogen sulfide emission and ammonia emission during the composting process of kitchen waste. On the basis of adding corn straw, adding activated carbon + zeolite or bacteria agent for municipal solid waste (SUKAZYE) can both effectively reduce the emissions of ammonia in the composting process of kitchen waste and the emission reduction rate can reach more than 70%. The addition of β-cyclodextrin and bacteria agent for municipal solid waste (SUKAZYE) can reduce the emissions of hydrogen sulfide in the composting process of kitchen waste, and on the basis of adding straw they can reduce the hydrogen sulfide emission by more than 30%. The results can supply a reference for selecting additives to control odor emissions during kitchen waste composting.

       

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