刘少康, 孙平, 刘军恒, 嵇乾, 吕俊翔. 铈基燃油催化剂改善柴油机颗粒物捕集器再生效果[J]. 农业工程学报, 2016, 32(1): 112-117. DOI: 10.11975/j.issn.1002-6819.2016.01.015
    引用本文: 刘少康, 孙平, 刘军恒, 嵇乾, 吕俊翔. 铈基燃油催化剂改善柴油机颗粒物捕集器再生效果[J]. 农业工程学报, 2016, 32(1): 112-117. DOI: 10.11975/j.issn.1002-6819.2016.01.015
    Liu Shaokang, Sun Ping, Liu Junheng, Ji Qian, Lü Junxiang. Ce-based fuel borne catalyst enhancing regenerative effect of diesel particulate filter[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2016, 32(1): 112-117. DOI: 10.11975/j.issn.1002-6819.2016.01.015
    Citation: Liu Shaokang, Sun Ping, Liu Junheng, Ji Qian, Lü Junxiang. Ce-based fuel borne catalyst enhancing regenerative effect of diesel particulate filter[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2016, 32(1): 112-117. DOI: 10.11975/j.issn.1002-6819.2016.01.015

    铈基燃油催化剂改善柴油机颗粒物捕集器再生效果

    Ce-based fuel borne catalyst enhancing regenerative effect of diesel particulate filter

    • 摘要: 颗粒捕集器(diesel Particulate filter,DPF)是目前公认的最有效的柴油机排气颗粒物后处理装置,为了去除DPF内部沉积颗粒,实现DPF再生,采用提高排气温度或催化燃烧的方法来促进颗粒物燃烧。该文采用环烷酸铈溶剂作为燃油催化再生添加剂(fuel borne catalyst,FBC),对柴油机DPF的再生平衡温度、压降特性和燃烧灰烬等进行试验研究。试验结果表明:DPF再生平衡温度因FBC的催化作用从500 ℃以上下降到约450 ℃,从而增加了颗粒捕集器的颗粒储备能力,并能够有效再生;柴油机燃油消耗率随着排气背压的增加而上升;燃用FBC测试燃油时DPF前后压差较纯柴油上升缓慢,其达到排气背压再生阀值的周期变长;同时,随再生次数的增多,再生后DPF的前后压差呈线性增加,捕集效率却逐渐提高。该文采用燃油添加剂可以明显降低颗粒的着火点。结合电加热装置,可有效提高DPF的再生效果,有效过滤柴油车尾气中的颗粒物,对柴油车尾气净化及环境保护具有十分重要的意义。

       

      Abstract: In order to meet the emission regulations, the diesel particulate filter(DPF)is a promising solution,which can trap more than 90% Particulate Matter(PM) from the exhaust gas.As an effective way of reducing the diesel particulates, DPF has already been developed and manufactured in foreign diesel engine market.Fuel borne catalyst(FBC) additive makes particulates deposite inside the porous wall regenerated by the active metal component in fuel, which can reduce the particulate ignition temperature, and also the peak temperature of the regeneration process.A fundamental study on catalytic regeneration progress of FBC additives within DPF is performed, which has the important theory signification and engineering value.The naphthenic acid cerium is selected as fuel borne catalyst(FBC)additive, and the influences of these test fuels on regeneration characteristic of a fuel borne catalyst with regenerative type of diesel particulate filter (FBC-DPF), have been investigated.The experimental engine is a 186FA diesel engine, and the study DPF is a honeycomb ceramic filter matching electrical heating regeneration system.The DPF collection and regeneration experiment is conducted in the condition that the diesel engine speed is 2800 r/min, the mean indicated pressure is 0.46MPa, and DPF inlet temperature is 510℃.The experiment includes four parts: regeneration balance temperature of DPF(when trapping efficiency and combustion rate of PM in DPF are identical, and pressure drop of DPF remains stable.At this time the inlet temperature of DPF is called regeneration balance temperature of DPF.), pressure drop characteristics, PM loading characteristics and filtration efficiency of DPF.Then the DPF regeneration strategy was studied and developed, which contained 3 parts: DPF regeneration timing, temperature rising strategy and DPF regeneration process control.The results showed that adoption the method of fuel additives can obviously decrease DPF regeneration temperature.In the low load condition, no additives DPF couldn′t achieve regeneration, while under the same condition with additives, DPF regeneration at 450℃ has already begun.The fuel specific consumption rises with increase of exhaust back pressure.When the exhaust back pressure increases from 0 to 14 kPa, the fuel specific consumption rises by 4.7%.The back pressure of FBC-DPF increases linearly along with accumulation of the PM compared with diesel fuel.On the previous experiment condition, when using the pure diesel, pressure drop of DPF increasing to 14 kPa needs 1170 minutes.While using the FBC-added diesel fuel, pressure drop of DPF increaseing to regenerative limiting value needs 1980 minutes.Using the FBC-added diesel fuel can extend the period of regeneration threshold, and increase the particulate storing capacity and regeneration ability of the DPF.Owing to the pressure drop characteristics of DPF regeneration process, particle in the deep bed filtration layer is firstly oxidized, and the filter cake layer of DPF wall surface also begins to oxidize in the process of DPF regeneration.As filter cake layer has turned thinner and fractured slowly, pressure drop of DPF decreases rapidly.Broken pie carrier particles penetrate into the wall, which is fully contacted with DPF and fully oxidized.Wall-flow diesel particulate filter filtrates particulate matter by diffusion, interception, gravity and interia.The back pressure of regenerated DPF increases linearly with regeneration times, and the trapping efficiency of DPF on PM increases at the same time.On the whole, using the FBC-added diesel fuel can obviously decrease DPF regeneration temperature, which can enhance the effect of DPF regeneration.It can filter PM emitted by diesel engine efficiently combining with electrical heating device, which has a reference for environmental protection and purifying diesel exhaust.

       

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