陈良元, 韩李锋, 李旭, 许冰洋, 钱玉梅, 朱文魁. 茄子片热风干燥收缩特性及其修正的湿分扩散动力学模型[J]. 农业工程学报, 2016, 32(15): 275-281. DOI: 10.11975/j.issn.1002-6819.2016.15.038
    引用本文: 陈良元, 韩李锋, 李旭, 许冰洋, 钱玉梅, 朱文魁. 茄子片热风干燥收缩特性及其修正的湿分扩散动力学模型[J]. 农业工程学报, 2016, 32(15): 275-281. DOI: 10.11975/j.issn.1002-6819.2016.15.038
    Chen Liangyuan, Han Lifeng, Li Xu, Xu Bingyang, Qian Yumei, Zhu Wenkui. Structural shrinkage characteristics and modified moisture diffusion kinetics model of sliced eggplant dried by hot air[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2016, 32(15): 275-281. DOI: 10.11975/j.issn.1002-6819.2016.15.038
    Citation: Chen Liangyuan, Han Lifeng, Li Xu, Xu Bingyang, Qian Yumei, Zhu Wenkui. Structural shrinkage characteristics and modified moisture diffusion kinetics model of sliced eggplant dried by hot air[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2016, 32(15): 275-281. DOI: 10.11975/j.issn.1002-6819.2016.15.038

    茄子片热风干燥收缩特性及其修正的湿分扩散动力学模型

    Structural shrinkage characteristics and modified moisture diffusion kinetics model of sliced eggplant dried by hot air

    • 摘要: 为了研究收缩特性对切片果蔬对流干燥过程水分有效扩散系数的影响,以切片茄子作为研究对象,结合密度分析、扫描电镜分析、压汞测试等方法,分析了热风干燥过程切片茄子内孔容积、孔隙结构及体积的收缩变化规律,建立了考虑其收缩特性的水分扩散动力学模型,并分析了干燥收缩行为对切片茄子干燥动力学的影响。研究结果表明,热风干燥过程切片茄子内孔容积随水分比的减小近似呈线性降低趋势,不同热风干燥温度对其降低趋势影响不大;干燥初期切片茄子孔隙以105 nm以上的大孔为主,干燥过程孔隙收缩导致105 nm以上的大孔孔隙逐渐消失,105 nm以下的中小孔隙比例逐渐增加,峰值孔径也从约1.5×105 nm减小至4×104 nm;Hatamipour及Quadratic收缩方程均能较好地描述切片茄子热风干燥过程中的体积收缩特性;考虑切片茄子体积收缩对干燥传质过程的影响,采用Quadratic收缩方程对基于Fick第二定律的扩散模型修正后,切片茄子干燥过程水分有效扩散系数明显降低,表观活化能由20.69 kJ/mol增大至25.76 kJ/mol,表明干燥过程中的收缩导致水分扩散内部阻力增大。因此,水分有效扩散系数在不考虑干燥收缩对动力学影响时将被明显高估。该研究结果能为更客观地评价可变形多孔物料的干燥特性、优化其干燥工艺提供参考。

       

      Abstract: Hot air drying is commonly used to dehydrate fruit and vegetable slices in the agricultural product processing industries.So it is important to establish a kinetic model of the drying process that can accurately describe heat and mass transfer for optimizing processes, improving drying quality and saving drying energy.However, fruits and vegetables as porous media, always have a significant volume shrinkage during drying, and many previous studies of porous media ignored the characteristics of macro-volume shrinkage with drying or more directly simplified the porous media as the materials just with a rigid skeleton, which was contributed to the situation in which there was no further analysis about the effects of the shrinkage on drying processing.Furthermore, eggplant, one of the main vegetable varieties in China, due to its short shelf life, was often sliced and dehydrated to preserve its equality instead of being eaten freshly, and the texture of eggplant is soft and porous, so its dry tissue is easy to shrink and deform during the whole hot air drying.Hence, in this paper, eggplant was chosen as the experimental porous material, and the testing methods, such as the density analysis, scanning electron microscope (SEM) analysis and mercury intrusion testing, were used to analyze the variation of sliced eggplant pore volume, structure and volume shrinkage during hot air drying.At the same time, a moisture diffusion kinetic model based on the shrinkage characteristics of the slices was established to study the effect of shrinkage on drying kinetics of sliced eggplant.As a result, internal pore volumes of the eggplant approximately linearly decreased with its moisture rate decreasing, but they were not obviously changed with hot air temperatures.During the drying processing, the proportion of the pores of smaller than 105 nm gradually increased, however, the pores of bigger than 105 nm that were dominant in the early stage of the drying gradually disappeared due to porous shrinkage caused by moisture loss when drying.In addition, according to the results of mercury intrusion testing, the peak of pore size decreased from 1.5×105 to 4×104 nm.In consideration of shrinkage properties of porous media, this work explored the influence of drying temperature on internal structure of sliced eggplant and modified the drying kinetic models based on the Fick’s second diffusion law.Among those volume shrinkage models, Hatamipour model and Quadratic model could describe the real volume shrinkage better.After modifying the drying model based on Fick’s second law with Quadratic shrinkage model that was selected as the best empirical shrinkage model due to its simplicity and accuracy, the convective drying kinetic model of eggplant slices could fit the experimental results more accurately.Moreover, apparent activation energy (AAE) of the sliced eggplant increased from 20.69 to 25.76 kJ/mol, indicating that the shrinkage of eggplant increased the mass transfer resistance during the process, which proved that the effective diffusion coefficient of water was overestimated obviously when not considering the influence of shrinkage on dynamics during the drying.In short, the modified kinetics models can provide a more objective evaluation of the drying characteristics of the deformable porous material and the reference for the optimization of its drying process.

       

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