徐建国, 张森旺, 徐刚, 顾震, 李华栋. 莲子热风干燥过程对其淀粉热特性及凝胶化的影响[J]. 农业工程学报, 2017, 33(17): 298-303. DOI: 10.11975/j.issn.1002-6819.2017.17.039
    引用本文: 徐建国, 张森旺, 徐刚, 顾震, 李华栋. 莲子热风干燥过程对其淀粉热特性及凝胶化的影响[J]. 农业工程学报, 2017, 33(17): 298-303. DOI: 10.11975/j.issn.1002-6819.2017.17.039
    Xu Jianguo, Zhang Senwang, Xu Gang, Gu Zhen, Li Huadong. Starch thermal property and gelatinization of lotus seeds during hot air drying[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(17): 298-303. DOI: 10.11975/j.issn.1002-6819.2017.17.039
    Citation: Xu Jianguo, Zhang Senwang, Xu Gang, Gu Zhen, Li Huadong. Starch thermal property and gelatinization of lotus seeds during hot air drying[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(17): 298-303. DOI: 10.11975/j.issn.1002-6819.2017.17.039

    莲子热风干燥过程对其淀粉热特性及凝胶化的影响

    Starch thermal property and gelatinization of lotus seeds during hot air drying

    • 摘要: 为解决莲子干燥过程中淀粉形态结构变化造成莲子结壳、硬化,不利于干燥以及复水难、易返生问题,该文利用差示扫描量热技术(differential scanning calorimetry, DSC)对新鲜莲子以及不同热风干燥(70、80、90 ℃)莲子的淀粉热特性与凝胶化过程进行了研究。研究发现,莲子淀粉在低水分环境(42.2%,以质量比计)时存在2个明显的吸热峰,高水分环境(71.1%,以质量比计)时存在1个明显的吸热峰;莲子在干燥过程中不断失水,并伴随着淀粉凝胶化。方差分析(analysis of variance,ANOVA)表明,高温干燥显著影响莲子淀粉的热特性,其淀粉凝胶化温度(峰起温度To、峰顶温度Tp以及峰止温度Te)部分显著升高。相同干燥条件下,莲子淀粉糊化焓ΔH受水分显著影响,但干燥温度、升温速率对其影响不显著(P>0.01)。采用Kissinger、Crane方程获得了淀粉凝胶化动力学参数(活化能Ea、指前因子Z以及反应级数n)。莲子淀粉的非等温凝胶化反应可近似为一级反应,高温干燥后其Ea值出现增加,并随着水分增加呈现降低趋势。研究结果可为确定莲子高品质干燥工艺以及干莲子、莲子淀粉后续加工过程提供技术支持。

       

      Abstract: Abstract: Lotus (Nelumbo nucifera), an aquatic crop, is an important economic plant in Asia and Africa. Lotus seeds are popular food ingredients to East Asian cuisine and are used extensively in traditional Chinese medicine and in Chinese desserts. There is rich source of C-type starch in lotus seeds. Starch gelatinization often occurs when starch granules are heated in an aqueous medium, a phase transition from an ordered to a disordered state. Starch gelatinization affects texture, nutritional value and porosity, which changes moisture diffusivity of porous materials significantly. On the other hand, gelatinized starch tends to an ordered crystalline structure during storage, which is termed retrogradation that affects acceptability and shelf life of starchy food. Drying is one of the major processes for dried lotus seeds, which could suppress activities of microorganisms, enzymes or ferments and maintain its nutrition content. Hot air drying is a complex process of heat and mass transfer simultaneously. A better understanding of starch thermal property and gelatinization of lotus seeds during hot air drying should help improve product quality and efficiency of drying process. The gelatinization properties of starch extracted from lotus seeds dried at different temperature (70, 80, 90 ℃) were determined at various water contents varied from 42.2% to 71.1% (g/g). and heating rates(5, 10, 15 ℃/min) by differential scanning calorimetry (DSC) in this study. DSC thermograms were determined from 40 to 120 ℃. DSC analysis revealed that a single endotherm denoted as G is observed in lower temperature region (60-80 ℃) when starch is heated in excess water of 71.1%w/w, and two combined endothermic peaks (G and M) are exhibited at 42.2% g/g. All gelatinization transition temperature, such as onset temperature (To), peak temperature (Tp) and end temperature (Te), increased with drying temperature and heating rate significantly. The gelatinization enthalpy (ΔH) of lotus seed starch increased with water content significantly and no significant difference was observed for either drying temperature or heating rate (P>0.01). The kinetic parameters (reaction order (n), frequency factor (Z) and activation energy (Ea)) were determined using Kissinger equation and Crane equation at different water. First-order reaction kinetics described non-isothermal gelatinization process of lotus seed starch well. Ea values decreased with water content from 42.2% to 71.1% were influenced by water content and drying temperature, and Ea values of lotus seed starch dried at 70 and 80 ℃, separately, were higher than those of starch extracted from fresh lotus seed dried at 20 ℃. Lotus seed starch gelatinization occurs throughout the hot air drying process, especially at higher drying temperature and at higher water content varied from 63%w.b. to 45%w.b.. This study would be helpful in optimization of lotus seeds drying process and in application of lotus starch in food industry.

       

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