杨松, 马泽慧, 王磊, 罗茂泉. 躺滴法测量干湿循环条件下土壤固-液接触角的滞后特性[J]. 农业工程学报, 2018, 34(2): 114-119. DOI: 10.11975/j.issn.1002-6819.2018.02.015
    引用本文: 杨松, 马泽慧, 王磊, 罗茂泉. 躺滴法测量干湿循环条件下土壤固-液接触角的滞后特性[J]. 农业工程学报, 2018, 34(2): 114-119. DOI: 10.11975/j.issn.1002-6819.2018.02.015
    Yang Song, Ma Zehui, Wang Lei, Luo Maoquan. Hysteresis characteristics of soil solid-liquid contact angle measured by sessile drop method during wetting-drying cycles[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(2): 114-119. DOI: 10.11975/j.issn.1002-6819.2018.02.015
    Citation: Yang Song, Ma Zehui, Wang Lei, Luo Maoquan. Hysteresis characteristics of soil solid-liquid contact angle measured by sessile drop method during wetting-drying cycles[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(2): 114-119. DOI: 10.11975/j.issn.1002-6819.2018.02.015

    躺滴法测量干湿循环条件下土壤固-液接触角的滞后特性

    Hysteresis characteristics of soil solid-liquid contact angle measured by sessile drop method during wetting-drying cycles

    • 摘要: 接触角滞后是使土壤的土水特征曲线产生滞后现象的主要因素之一,而土水特征曲线的滞后特性是土壤干湿循环的显著特征。该文采用混合制样法制备不同接触角的土样,通过躺滴法对干湿循环过程中土体的固-液接触角随时间的变化关系进行测量,结果表明:随着土样表面固滴的蒸发,其固-液接触角是不断减小的,且初始接触角越大,固滴完全蒸发所用的时间越长,黏土接触角随时间变化关系曲线呈线性,而砂土的则表现出一定的非线性。不论土体的初始接触角多大,临近固滴蒸发结束,接触角都会变为0,且整个蒸发过程中固-液-气三相接触线不发生移动,固-液接触面积保持不变。试验结果证实了土壤脱湿过程把固-液接触角假设为0是合理的,并且可以断定接触角滞后特性也可能是非饱和土土水特征曲线在反复干湿循环下滞回圈不断减小的原因之一。

       

      Abstract: Abstract: The contact angle hysteresis is one of the main causes of soil water characteristic curve (SWCC) hysteresis in unsaturated soil, the hysteresis of SWCC is a remarkable feature of soil under wetting and drying cycles. In this study, we prepared soil samples with different contact angles by adding repellent agents (octadecylamine) and found that the more the content of the water repellent agents, the greater the contact angle between the soil particles and the pore water. Contact angle measurement test were designed at the same time, drying-wetting cycles of soil were reflected in the test. Droplet 1 was the initial state of the droplet, droplet 2 was a little drop formed after droplet 1 evaporation immediately, and droplet 3 was a little drop formed 24 hours after droplet 2 evaporation. The test results showed that, the contact angles of sand were greater than the clay with the same water repellent agents content, this was mainly because of the geometrical shapes of the soil particles. In all of the soil samples, the contact angles of soil particles and the pore water decreased continuously during the evaporation process, until the contact angle became 0. At this time, the droplets were completely vaporized. The change of the contact angle on clay surface had a linear relation with time, but it was a nonlinear on sand surface. In the same samples, the evaporation time of droplet 1 was longer than droplet 2 and droplet 3 with the same liquid volume, the time spent in droplet 2 and droplet 3 complete evaporation was relatively close, but droplet 3 took a little more time to evaporation than droplet 2, this meant initial contact angle may affect the evaporation velocity of the soil. The larger the initial contact angle, the longer the evaporation time of the droplet would be. Either sand or clay, the contact angle of droplet 1 was greater than droplet 2 and droplet 3. This was because that the contact angle of droplet 1 was measured on the fully dry sample surface. The contact angle of droplet 2 was measured on the sample surface when soil particles were covered by water films from the droplet 1. The contact angle of droplet 3 was measured on the state in which the free water was evaporated completely. The initial contact angle of the three droplets reflected the contact angle of the soil under different initial conditions of wetting drying cycles. The water films of soil particles which the droplet 1 correspond to were the thinnest and droplet 2 correspond to be the thickest. There were three stages of droplet evaporation on a continuous solid surface:Initial stage, pinning stage and slipping stage. The evaporation mode of soil particles only existed in the initial stage and pinning stage, and there was no slip stage. That was, no matter how lager the initial soil contact angle was, by the end of the droplet evaporation, contact angle would be 0. In the whole evaporation process, the three-phase contact line did not move, and the solid-liquid area remained unchanged. The experiment confirmed that it was reasonable to suppose the contact angle was zero during soil drying, the contact angle hysteresis was one of the reasons why SWCC hysteresis loops became small during wetting-drying cycles.

       

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