张雨, 王浚浩, 马中青, 周涵芝, 杨优优, 张文标. 温度对竹材烘焙过程中气固液三相产物组成及特性的影响[J]. 农业工程学报, 2018, 34(18): 242-251. DOI: 10.11975/j.issn.1002-6819.2018.18.030
    引用本文: 张雨, 王浚浩, 马中青, 周涵芝, 杨优优, 张文标. 温度对竹材烘焙过程中气固液三相产物组成及特性的影响[J]. 农业工程学报, 2018, 34(18): 242-251. DOI: 10.11975/j.issn.1002-6819.2018.18.030
    Zhang Yu, Wang Junhao, Ma Zhongqing, Zhou Hanzhi, Yang Youyou, Zhang Wenbiao. Effects of torrefaction temperature on composition and characteristics of gas-solid-liquid three-phase products in bamboo torrefaction process[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(18): 242-251. DOI: 10.11975/j.issn.1002-6819.2018.18.030
    Citation: Zhang Yu, Wang Junhao, Ma Zhongqing, Zhou Hanzhi, Yang Youyou, Zhang Wenbiao. Effects of torrefaction temperature on composition and characteristics of gas-solid-liquid three-phase products in bamboo torrefaction process[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(18): 242-251. DOI: 10.11975/j.issn.1002-6819.2018.18.030

    温度对竹材烘焙过程中气固液三相产物组成及特性的影响

    Effects of torrefaction temperature on composition and characteristics of gas-solid-liquid three-phase products in bamboo torrefaction process

    • 摘要: 烘焙预处理可有效降低生物质原料的含水率和O/C比、提高能量密度、可磨性和疏水性,进而减少热解油中水分和含氧化合物的含量,改善生物油的稳定性和品质。该文采用程序控温管式炉、热重-红外联用仪(TGA-FTIR)和快速热解-气质联用仪(PY-GC/MS)等开展生物质烘焙试验研究,研究烘焙温度(210、240、270和300 ℃)对毛竹烘焙过程中气、固、液三相产物的特性影响。试验结果表明:(1)烘焙固体产物:随烘焙温度升高,固体产物中固定碳和C元素含量显著增加,使得原料的热值从18.85 MJ/kg增加至23.12 MJ/kg,能量密度增加;O元素含量显著减少,使得O/C比值从0.74降低至0.42。(2)烘焙气体产物:烘焙气体成分主要为H2O、CO2、CO和CH4组成,其中CO2含量最高,其次为H2O、CH4和CO,所有气体产物含量随烘焙温度的升高而逐渐增加。(3)烘焙液体产物:烘焙液体产物主要由酸类、酮类、呋喃类、酚类以及醛类等有机物构成,其中酸类、酚类和呋喃类相对含量较高,最高可达20.34%、22.05%和31.42%,酮类、醛类含量相对较少,分别占10.43%与8.26%,随烘焙温度升高,酸类含量先增加后减少,呋喃类、酚类、酮类含量逐渐增加,醛类含量变化规律不显著。(4)基于对烘焙气、固、液体产物分析可知,竹材中的氧元素主要以H2O、CO2、CO和有机酸等形式脱除,烘焙预处理能有效提高竹材能量密度,去除水分与含氧化合物,提高烘焙固体产物的利用价值。研究结果可为竹材能源化利用提供参考。

       

      Abstract: Abstract: Bamboo is a typical agricultural and forestry biomass resource in China, which has the advantage of short growth cycle, high yield, abundant reserves. However, biomass has the disadvantages of high water content, high O/C ratio, poor grinding performance and low energy density. Torrefaction is a mild pre-pyrolysis process which operates at normal pressure, inert gas and lower temperature (200 to 300℃). Torrefaction pretreatment can effectively improve the properties of biomass, such as increasing the heating value or energy density, reducing the moisture content and O/C ratio, and improving the grinding and hydrophobicity. By these upgraded properties, the torrefaction pretreatment can also reduce the content of moisture and oxygen-containing compounds in the bio-oil, increase the heating value of bio-oil, and improve the quality and stability of bio-oil. In this paper, bamboo torrefaction was carried out in a furnace with programmed temperature controlling, Thermogravimetric analyzer coupled with Fourier transform infrared spectrometry (TGA-FTIR), pyrolyzer coupled with gas chromatography/mass spectrometer (Py-GC/MS) at different temperatures of 210, 240, 270 and 300℃. Then the effect of torrefaction temperature on the properties of the gas, solid, and liquid products was studied in order to reveal the torrefaction mechanism. The results showed that: (1) When the torrefaction temperature increased, the content of fixed carbon and C in the solid product increased significantly, resulting in an increasing of the calorific value and energy density from 18.85 MJ/kg to 23.12 MJ/kg. The oxygen content was significantly reduced, resulting in a decrease of the O/C ratio from 0.74 to 0.42. (2) Based on the FTIR analysis, the gas composition was mainly composed of H2O, CO2, CO, and CH4, and CO2 was the dominant gas, followed by H2O, CH4 and CO, and all gas content gradually increased as the torrefaction temperature increased; (3) Based on the Py-GC/MS analysis, the liquid products are mainly composed of acids, ketones, furans, phenols, aldehydes and other organic compounds. Acids, phenols and furans were the dominant components with the content of the 20.34%, 22.05% and 31.42% respectively. However, the contents of ketones and aldehydes were relatively lower, which are 10.43% and 8.26%, respectively. As the torrefaction temperature increases, the content of acid increases first and then decreases. The contents of furans, phenols, and ketones increase gradually, and the aldehyde content does not change significantly. (4) Based on the properties of gas, solid, and liquid products, the oxygen in the bamboo was mainly removed in the form of gas components (H2O, CO2 and CO, etc.) and oxygen-containing organic components (acids, phenols and furans, etc.). The torrefaction pretreatment can improve the content of C in the solid product and reduce the oxygen content, thereby increasing the energy density of bamboo. In addition, torrefaction can remove moisture and oxygen-containing compounds in bio-oil, and eventually increase the application value of biomass. This study provides basic data for the energy use of bamboo.

       

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