于殿宇, 王彤, 唐洪琳, 陈俊, 江连洲, 韩富江, 吴非. 挤压法制备富钙强化重组大米的工艺优化及其结构表征[J]. 农业工程学报, 2018, 34(22): 291-298. DOI: 10.11975/j.issn.1002-6819.2018.22.036
    引用本文: 于殿宇, 王彤, 唐洪琳, 陈俊, 江连洲, 韩富江, 吴非. 挤压法制备富钙强化重组大米的工艺优化及其结构表征[J]. 农业工程学报, 2018, 34(22): 291-298. DOI: 10.11975/j.issn.1002-6819.2018.22.036
    Yu Dianyu, Wang Tong, Tang Honglin, Chen Jun, Jiang Lianzhou, Han Fujiang, Wu Fei. Process optimization and structure characterization of calcium-fortified recombinant rice prepared by extrusion[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(22): 291-298. DOI: 10.11975/j.issn.1002-6819.2018.22.036
    Citation: Yu Dianyu, Wang Tong, Tang Honglin, Chen Jun, Jiang Lianzhou, Han Fujiang, Wu Fei. Process optimization and structure characterization of calcium-fortified recombinant rice prepared by extrusion[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(22): 291-298. DOI: 10.11975/j.issn.1002-6819.2018.22.036

    挤压法制备富钙强化重组大米的工艺优化及其结构表征

    Process optimization and structure characterization of calcium-fortified recombinant rice prepared by extrusion

    • 摘要: 为提高碎粳米的利用率并制备出富含钙元素的重组强化大米,该文以粳米碎米为原料,添加乙酸钙作为强化剂,通过使用挤压法制备富含钙元素的重组强化大米。试验以钙强化大米质构特性为指标,对挤压工艺参数进行响应面优化,得到最佳工艺参数为:机筒温度100 ℃,螺杆转速85 r/min,质量含水率20.0%。在最佳工艺条件下得到的钙强化大米硬度为13.38 N,弹性为0.67 mm,黏着性为0.64 mJ,咀嚼性为851.51 mJ,接近普通粳米的质构特性,其钙质量分数为108.2 mg/(100 g)。经X射线衍射表明强化米的结晶度明显减少,通过扫描电镜表征发现其外表面粗糙呈现不规则形状,并产生聚集现象,糊化温度降低。将其按1:12的比例添加到粳米中,钙质量分数为18.02 mg/(100 g),可提高人体对钙的摄入。

       

      Abstract: Calcium is the most abundant element in the human bodyʼs inorganic elements. It is an important component of human bones and teeth that has important physiological functions. Calcium has the functions of strengthening the soft tissue springness and toughness, reducing the excitability of nerve cells, promoting the activities of various enzymes in the body, maintaining the acid-base balance, and participating in blood coagulation. The calcium deficiency can cause rickets, osteoporosis and many other diseases. However, at present, our people’s intake of calcium is still far from enough. Rice is the most important staple food in people's daily life. It is rich in nutrients and can provide the body with the daily energy needed. However, the protein content in rice is low, and the proportion of amino acids is unreasonable. With the improvement of rice processing, many valuable nutrients are lost during the grinding and polishing process. At present, the main methods of rice nutrition enhancement include soaking, surface coating and extrusion. Due to large losses of nutrients, incomplete impregnation, and high cost, soaking and surface coating methods are rarely used for nutrition enhanced rice production. Extrusion is a high-temperature, short-term treatment process that combines mixing, stirring, crushing, heating, sterilizing, extrusion, and forming as a whole. It is widely used in the food industry. Due to the high temperature, high pressure, and high shear forces during the extrusion process, macromolecular substances such as starch and proteins in rice are cut into small molecules. The broken glutinous rice was used as raw material, calcium acetate was added as a nutritional enhancer, and the extrusion method was used to prepare a recombinant nutrient-fortified rice rich in calcium. In the experiment, the texture of calcium fortified rice was used as an index to optimize the process parameters of the extrusion process. The optimum process parameters were as follows: barrel temperature 100 ℃, screw speed 85 r/min, and water content 20.0%. Under the optimum process conditions, the calcium-fortified rice had a hardness of 13.38 N, an springness of 0.67 mm, an adhesiveness of 0.64 mJ, and a chewiness of 851.51 mJ, which was close to the texture characteristics of ordinary glutinous rice. In order to test the reliability of the results obtained under the optimized conditions of the response surface, the hardness obtained by parallel test was 13.24 N, the springness was 0.65 mm, the adhesiveness was 0.63 mJ, the chewiness was 855.21 mJ. the fit between the predicted value of the response surface and the experimental value was good, which confirmed the validity of the model. By measuring the texture of commercially available glutinous rice, the hardness was 11.90 N, the springness was 0.78 mm, the adhesiveness was 0.72 mJ, and the chewiness was 798.50 mJ. The texture characteristics of calcium-fortified recombinant rice were close to that of glutinous rice. The calcium content of the fortified rice was 108.2 mg/(100 g), which is much higher than 10.5 mg/(100 g) of common glutinous rice. Studies have shown that the calcium content of calcium fortified rice prepared by the extrusion method was much more than that of normal glutinous rice, and its hardness, springness, chewiness and adhesiveness were superior to those of normal rice. The X-ray diffraction showed that the crystallinity of the fortified rice was significantly reduced and the fortified rice had a strong diffraction peak near the diffraction angle 2θ of 29°, indicating that the calcium content in the fortified rice was improved. It was found by scanning electron microscopy that the outer surface of the fortified rice was rough and irregular, the aggregation phenomenon occurred, and the gelatinization temperature decreased. The extrusion process had a significant effect on the gelatinization characteristics of rice and the viscosity of rice after extrusion was not significantly changed with time, indicating that its starch stability was better. Adding it to glutinous rice with a ratio of 1:12, the rice had a good appearance with a calcium content of 18.02 mg/100g, which was favorable for industrial production and solving the problem of insufficient calcium intake.

       

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