基于NB-IoT技术的土壤重金属检测仪设计与验证

    Design and verification of soil heavy metal detector using NB-IoT technology

    • 摘要: 为解决土壤重金属检测准确度较低、实时性差以及数据分散的问题,该研究设计了一种基于窄带物联网(Narrow Band Internet of Things,NB-IoT)技术的土壤重金属检测仪。自主研发高准确度能量色散X射线荧光光谱仪,将测量得到的数据通过NB-IoT实时上传到数据集成云平台。设计试验探究了该设备的最佳测试时间、预热时间。结果显示:在预热30 min后以180 s的测试时间测量样品,仪器具有最佳重复性。设计试验验证该设备的准确度,使用该设备、奥林巴斯Vanta Element-S、实验室化学方法针对同一批四川土壤进行了多次采样比较研究,结果显示:Cd、Hg、As、Pb、Zn、Cu测量值都具有较高准确度,测量As、Cr、Hg、Pb元素时比Vanta Element-S更接近真实值。测量国家标准土样,对比样品标准值,7种元素中Cr、Cu、Pb、Zn的平均相对误差非常小,分别为4.6%、7.5%、3.8%、14.2%。其余3种元素As、Cd、Hg相对误差分别为55.5%,55.7%,37.2%。该设备能够准确、稳定、实时的检测出土壤较高含量的重金属元素含量值并且将数据汇总到云平台,具有较为优异的实时性及数据集成能力,在大规模土壤检测分析场合具有一定的推广价值。

       

      Abstract: Abstract: An Energy Dispersive X-Ray Fluorescence (EDXRF) monitor was here developed to detect the soil heavy metal using narrow band internet of things (NB-IoT). The scattered data was also real-time uploaded during detection. The instrument consisted of a TUB00050-AG2 X-ray tube, variable windows collimator, a Vitus H30 40 mm2 detector, an LTC2269 analog to digital converter, and an NB-IoT communication module. The X-ray tube turned on the high voltage and filament current under the control of the main chip, thereby producing bremsstrahlung X-rays, where the electrons bombarded the silver target under a strong electric field. The X-ray was then converted to the object ray with the corresponding peak by the filter collimator. The object ray irradiated the center of the sample by adjusting the divergence angle through the collimator. The fluorescence ray was then reflected on the receiving surface of the silicon drift detector with Compton and Rayleigh scattered rays. The detector converted the photon of the incident ray into the pulse signal for the subsequent step rising signal with the preamplifier. The signal was amplified, held, and sampled to generate the spectrum, and then data and location information were uploaded to the NB-IoT module. The final content of each element was obtained for the spectrum resolution, deviation correction. There were no packets loss, and connections instability during 10 000 times' uploading simulated data, indicating low power consumption and stable signal in the NB-IoT module. Better repeatability, real-time detection, and data integration were achieved in the variable light window collimator and communication means with NB-IoT, compared with other similar devices. The NB-IoT base station can widely be expected to support many devices and cover a large area. A general communication protocol of the Internet of things, MQTT, was set up with an NB-IoT module between the platform and instrument. A wide range of expansion support can realize the integration of multiple instruments and various measurement data. An experiment was also designed to explore the best test time and preheating time of the instrument, where five durations were set. It was found that the instrument performed well, as the duration increased, but some elements became unstable when the duration reached 240 s per sample. The best duration was determined to be 180 s in this case. Consequently, the instrument presented the best repeatability, when the sample was preheated for more than 30 min and the measurement time was 180 s. Three instruments were also fabricated to verify the measurement accuracy of the instrument with the soil samples from the same batch in Sichuan Province. The collected soil was used to prepare the standard samples after drying, grinding, sieving and pressing. This instrument and Olympus Vanta Element-S were compared to measure each sample 5 times. The soil samples were also characterized in a laboratory chemical analysis. It was found that the detection presented a high accuracy for the Cd, Hg, As, Pb, Zn, Cu, and other five elements. Particularly, the measured value of Cr was much more approximate to the true one, compared with Olympus Vanta Element-S. The average relative errors of Cr, Cu, Pb and Zn were 4.6%, 7.5%, 3.8% and 14.2%, respectively, indicating high accuracy. The relative errors of the remaining three elements As, Cd, and Hg are 55.5%, 55.7%, and 37.2%, respectively. The errors are relatively large and will be significantly reduced as the detector accuracy improves in the future. The device can widely be expected to accurately, stably and real-time detect the content of heavy metals in soil. Subsequently, the data can be summarized to the cloud platform, indicating an excellent real-time performance and data integration.

       

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