Abstract: The matric suction of saline soil is the driving force that causes water migration, and it is of great significance for exploring the mechanism of water and salt migration in saline frozen soil. In order to investigate the effect of phase transition of soil pore solution induced by temperature on the matric suction of saline soil, the matric suction of different types of saline soils was measured by pF meter under different temperature conditions. The natural soil was first washed to obtain the desalinized soil, then different salt mass ratios of sodium chloride and sodium sulfate (0:6, 4:2, 2:4, 6:0) were added into the desalinized soil to model the composite saline soil, the salt content and water content were set to 6% and 20%, respectively. Subsequently, the remolded saline soil was compacted into the test chamber (0.37 m×0.25 m×0.22 m), and its dry density was controlled at 1.6 g/cm³. Hydra Probe II and pF meter were embedded at 11cm of the sample to measure the liquid water content and matric suction versus temperature. Freezing-thawing box (TMS 9 018-R30), produced by Zhejiang Tomos company, was employed to control the experimental temperature by step cooling method. The temperature range was from 30 to -24 °C, and the temperature interval was 3 °C. The data was collected by CR300 at an interval of 6 h. When the experiment was complete, the temperature effect of saline soil matric suction was analyzed and the effect of water/salt phase transition was explored. The experimental results reveal that the matric suction of saline soil increases almost linearly with the decrease of temperature when no phase transition occurs, which is caused by surface tension and wetting coefficient. Different types of saline soils have different effects on the phase transition process of pore solution, resulting in significant differences in the matric suction of different types of saline soils. The mirabilite crystallizes at 19 °C and the second phase transition occurs at -9 °C for the composite saline soil with 2% NaCl+4% Na₂SO₄, and the phase transition of composite saline soil with 4% NaCl+2% Na₂SO₄ occurs at 11 and -16 °C.Sodium chloride can inhibit the occurrence of ice formation, then the matric suction caused by ice formation is reduced, and the segregated frost heave caused by water migration is restrained indirectly. Besides, sodium sulfate is prone to crystallization at positive temperatures, and ice is also produced in the secondary phase transition process, both salt crystallization and ice formation increase the matric suction in sodium sulfate soil, and water and salt redistribute in this process, salt expansion and frost heave are induced. For composite saline soil, sodium sulfate mainly affects the salt crystallization of the soil at a positive temperature, while sodium chloride mainly affects the ice formation of the soil at a negative temperature. The different proportions of the two salts cause significant differences in the salt crystallization temperature and the secondary phase transition temperature, resulting in more complex phase transition laws in composite saline soil, and it is more difficult to predict the matric suction of composite saline soil. In addition, this paper further explores the contribution of ice and salt crystallization to the variation of matric suction, providing effective references for a deeper understanding of the relationship between phase transition processes and matric suction in saline soils.