脲酶诱导碳酸钙沉积(EICP)减小三峡库区紫色土分离能力效果

    Performance of enzyme-induced carbonate precipitation (EICP) for reducing soil detachment capacity of purple soil in the Three Gorges Reservoir Area

    • 摘要: 为探究脲酶诱导碳酸钙沉积(enzyme-induced carbonate precipitation,EICP)减小三峡库区紫色土分离能力效果,该研究设置5个EICP浓度(0(CK对照)、0.5、1.0、1.5和2.0 mol/L)和6个养护时间(1、7、15、30、60和120 d),开展模拟冲刷试验分析土壤分离能力,通过表观黏聚力和碳酸钙含量变化阐明EICP作用下紫色土分离能力变化原因,并从微观角度揭示其减蚀机制。结果表明:与CK对照相比,EICP处理显著减小土壤分离能力,随着EICP浓度的增加,紫色土分离能力呈现先减小后增大的变化趋势,在浓度为1.5 mol/L时效果最佳;而随着养护时间的延长,紫色土分离能力呈现先快速减小再缓慢减小的变化规律,CK对照在前30天减小明显,EICP处理下在第7天时减幅明显,减幅占总减幅的85.79%~92.21%。表观黏聚力与碳酸钙含量随EICP浓度的增加先增大后减小,而随养护时间的延长分别呈持续增大和先增大后趋于稳定的变化趋势。EICP作用下紫色土碳酸钙聚集是引起分离能力降低的重要原因,表观黏聚力和碳酸钙含量与紫色土分离能力呈现显著指数函数关系(P<0.01),能够很好解释紫色土分离能力的变化。研究结果表明EICP能够有效减小紫色土分离能力,可为三峡库区水土流失治理提供理论指导。

       

      Abstract: The Three Gorges Reservoir Area (TGRA) has often suffered the most serious soil erosion in recent years. Soil erosion control still remains on the purple soil, the main soil type for the sloping farmland in this area. Among them, enzyme-induced carbonate precipitation (EICP) can rely on the urease enzymes to catalyze urea. Specifically, the urea can be decomposed into ammonium and carbonate anions, and then precipitated the calcium carbonate (CaCO3) with the presence of carbonate anions and external calcium sources. EICP has been proven to efficiently strengthen the soil for less infiltration, in order to restore the rock and heritage. A promising approach can be regarded to effectively control soil erosion. However, the effect of EICP on the soil detachment capacity is still far from clear, especially for the response of soil detachment to the EICP concentration and maintenance time. Therefore, this study aims to clarify the effect of EICP solution concentration and maintenance duration on the soil detachment capacity of purple soil in the Three Gorges Reservoir Area. The purple soil in the TGRA was taken as the research material. The scouring experiments were conducted under five EICP solution concentrations (0 (for control check), 0.5, 1.0, 1.5, and 2.0 mol/L) at six maintenance durations (1, 7, 15, 30, 60, and 120 d), in order to estimate the soil detachment capacity. Also, the apparent cohesion and calcium carbonate content were measured at different experiment conditions. Moreover, the SEM was employed to reveal the micro-mechanism of erosion reduction by EICP. The results indicated that the soil detachment capacity of purple soil significantly decreased with the application of EICP solution. Compared with the CK, the soil detachment capacity decreased by 19.63%-86.92%, 38.79%-89.41%, 48.13%-89.91%, and 31.78%-84.49%, respectively, at the EICP solution concentration of 0.5, 1.0, 1.5 and 2.0 mol/L, with the most pronounced effect at the concentration of 1.5 mol/L. Additionally, the soil detachment capacity decreased rapidly, whereas, the subsequent slowly decreased as maintenance duration increased. Compared with the maintenance for 1 d, the decreases at 7, 15, 30, 60, and 120 d were 19.79%-84.08%, 33.81%-87.80%, 87.27%-94.21%, 91.41%-93.18%, and 91.18%-92.77%, respectively. Moreover, the reduction amplitude in the soil detachment capacity accounted for 85.79%-92.21% of the total reduction amplitude at the maintenance duration of 7 d under the application of the EICP solution. The apparent cohesion and calcium carbonate content of purple soil showed a trend of increase followed by a decrease with the increase of EICP solution concentration. Compared with the CK, the apparent cohesion increased by 43.70%-77.43%, 58.54%-101.21%, 77.06%-135.68%, and 64.08%-87.86%, respectively, at the EICP solution concentration of 0.5, 1.0, 1.5 and 2.0 mol/L, while the calcium carbonate content increased by 10.29-17.35 times, 11.12-23.00 times, 12.00-29.59 times and 10.88-24.35 times, respectively. Additionally, the apparent cohesion increased by 10.46%-36.38%, 21.98%-46.46%, 35.12%-55.41%, 45.15%-65.49%, and 48.61%-72.76%, respectively, at the maintenance for 7, 15, 30, 60 and 120 d, compared with the maintenance for 1 d. The content of calcium carbonate increased by 54.17%-133.48%, 60.94%-134.39%, 61.98%-134.84%, 61.46%-134.84%, and 62.50%-135.29%, respectively, at the maintenance for 7, 15, 30, 60 and 120 d under the application of EICP solution, compared with the stable content in the CK. The increase amplitude in the apparent cohesion and calcium carbonate content accounted for 37.59%-59.56% and 78.26%-98.66% of the total increase amplitude, respectively, at the maintenance duration of 7 d. Additionally, the microscopic analysis exposed that the soil detachment capacity was reduced to aggregate the calcium carbonate in the soil surface under the application of EICP solution. Furthermore, the soil detachment capacity was better described by the apparent cohesion and calcium carbonate content with an exponential function. The findings can provide theoretical guidance to promote erosion control in the application of EICP on soil detachment of purple soil in the TGRA.

       

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