水热炭在土壤改良中的应用潜力与技术挑战

    Application potential and technical challenges of hydrochar in soil amelioration

    • 摘要: 近年来,水热炭在土壤改良中表现出巨大的应用潜力。为深入分析水热炭在土壤改良方面的应用潜力和技术挑战,该研究系统综述水热炭对土壤结构、pH值、电导率、阳离子交换总量、营养物质含量等理化性质的改善潜力,梳理了水热炭对土壤微生物多样性、功能基因及其代谢活性的强化效应,探讨了水热炭在土壤应用过程中面临的高植物毒性、低比表面积、重金属含量超标等技术挑战,汇总了洗涤、热处理、堆肥、老化等植物毒性去除技术,以及酸、碱、金属盐改性等表面性能优化措施,并指出:1)未来研究应权衡技术成本与生态价值间的关系,以选择更合适的水热炭应用技术方案;2)加强水热炭在土壤中应用的影响机制研究与环境风险评估;3)制定相关技术规范和标准,建立健全监测与评估体系,保障水热炭在土壤中应用的安全性与有效性。该研究可为水热炭在土壤改良方面的应用提供参考。

       

      Abstract: The soil on Earth is facing serious threats such as soil erosion, loss of soil organic carbon, nutrient imbalance, acidification, and compaction. It is of great strategic significance to implement effective soil improvement measures for maintaining soil quality and promoting sustainable agricultural development. This study reviewed the potential and technical challenges of hydrochar (a kind of biomass charcoal) in soil ameliaration. Biomass charcoal is an excellent soil amendment with high carbon content, large specific surface area, high porosity, and strong adsorption capacity, which can improve soil properties through various physical, chemical, and biological methods. Biomass charcoal can be divided into biochar and hydrochar based on the preparation methods. Compared to biochars, hydrochars have milder preparation conditions, lower energy consumption, higher carbon fixation efficiency, and higher carbonization yield, which had attracted more attention from researchers. Hydrothermal reactions are usually carried out in a closed hydrothermal reactor. By setting certain temperature and pressure conditions, the material undergoes a series of chemical reactions such as hydrolysis, deamination, decarboxylation, polymerization, and aromatization, rapidly transforming into solid, liquid, and gas products. The solid product is usually referred to as "hydrochar". The composition and characteristics of hydrochar vary with different raw materials and preparation conditions. At present, many researchers at home and abroad have converted crop residues, sewage sludge, algae residues, and livestock manure into hydrochar through hydrothermal carbonization treatment, and conducted extensive researches to explore their potential applications as soil amendments. Numerous literature studies have shown that the application of hydrochar significantly affects the physical and chemical properties of soil (soil density, particle structure, pH value, electrical conductivity, cation exchange capacity, nutrient content, etc.), enzyme activity (soil sucrase, dehydrogenase, urease activity, etc.), microbial community (richness and diversity of bacteria and fungi), and soil functional genes (C, N, P and other element cycling functional genes). But the improvement effect of different types of hydrochar on different types of soil varie. The application of hydrochar to improve barren soils such as saline alkali soil, sandy soil, red soil, and acidic soil has been proven to be effective, demonstrating its enormous potential in soil improvement. However, the high phytotoxicity and low specific surface area of native hydrothermal carbon limit its application in soil environments to some extent. In order to address the deficiencies of hydrochar, researchers have made numerous attempts in the detoxification and specific surface area expansion of hydrochar. Techniques such as washing, thermal treatment, and adding chemical agents in physicochemical methods, as well as composting and aging in biological methods, have been employed to detoxify hydrochar, successfully achieving higher seed germination rates and positive plant growth effects. However, these studies primarily focused on improving the apparent physiological and biochemical indicators of plants without delving into the specific mechanisms of various detoxification methods. Moreover, methods such as acid modification, alkali modification, and metal salt modification were also used to dope elements and graft functional groups onto the surface of hydrochar, resulting in increased specific surface area and adsorption capacity, which is beneficial for the absorption and storage of various nutrients. In addition, there are no specific standard limits on heavy metal content in hydrochar established internationally, yet the level of heavy metals in hydrochar is a limiting factor affecting its comprehensive utilization. In the future, it is urgent to develop relevant technical specifications and standards while establishing a comprehensive monitoring and evaluation system to ensure its safety and effectiveness, thereby promoting the scientific and rational application of hydrochar. This study provides valuable information for further research and practical applications of hydrochar in soil environments, thus driving the continuous innovation and development of this emerging technology.

       

    /

    返回文章
    返回