节水改造前后内蒙古河套灌区地下水水化学特征

    Hydrochemical characteristics of groundwater before and after water-saving reform in Hetao Irrigation District, Inner Mongolia

    • 摘要: 为了研究大型灌区节水改造后区域农田水环境的变化,该文通过对内蒙古河套灌区上中下游地下水进行系统取样分析,综合运用描述性统计、相关性分析、离子比例系数和图解法(包括H.И.托尔斯基汉方格图解法、Piper三角图示法和多矩形图解法(multi-rectangular diagrams,MRD)),全面系统地研究节水改造前(2007年)后(2008,2009年)内蒙古河套灌区地下水水化学的时空变异特征与3 a演变规律。结果表明:蒸发浓缩和阳离子交换是控制灌区地下水水质演变的主要水文化学过程;与2007年(节水改造前)相比, 2008和2009年HCO3-在河套灌区地下水中绝对含量由在阴离子中最小变为最大成为地下水的主要阴离子; Ca2+、Mg2+、HCO3-的变异系数相对较小,它们在地下水中含量相对稳定。Na+、Cl-、SO42-的变异系数较大,它们在地下水中的含量变化较大,是随环境因素而变化的敏感因子,是决定地下水盐化作用的主要变量。整个灌区地下水的主要化学类型为HCO3-Na型、SO4-Na型和Cl-Na型,Cl-Na型水和SO4-Na型水主要分布在灌区的上游和下游,HCO3-Na型水在灌区上中下游都有分布。与2007年(节水改造前)相比,2008年和2009年HCO3-浓度有所增加,Cl-和Na+的浓度有所减少,灌区地下水向着淡化,对作物危害减小的方向转变。全灌区地下水水化学类型时空变异十分复杂,沿着地下水总体水流的方向(灌区上游→灌区中游→灌区下游)Na+占主导地位的趋势越来越明显,在地下水化学类型上,2008年和2009年HCO3-在阴离子占主导地位的化学类型多于2007年(节水改造前)的。与皮伯三线图解法和H.И.托尔斯基汉方格图解法相比,多矩形图解法提供了更明晰、易懂的水化学类型的信息,对于处理复杂地下水化学系统,多矩形图解法的优点更为显著。研究结果为灌区节水改造规划实施对农田水环境的影响进行合理评价提供科学参考。

       

      Abstract: Abstract: The purpose of the research is to validate the water environment changes of regional soil after implementing the water-saving upgrading program. The background of this research is about program implementation of water-saving upgrading in North irrigation district. The groundwater samples were analyzed scientifically and systemically in Inner Mongolia Hetao irrigation district, then the descriptive statistics, the correlation matrices, the ratio coefficient of the main ions and the graphical method (including the H.И. diagram, the piper diagram and Multi-rectangular diagram) were utilized to gain the better understanding of the spatial-temporal variability of the characteristics and the evolution rule of groundwater hydrochemistry in Hetao irrigation district of Inner Mongolia. The results showed that evaporation concentration, lixiviation and cation exchange were the main hydrological chemical processes which controlled the evolution of groundwater quality in irrigation district. Compare with the 2007 (before water-saving upgrading), the absolute content of HCO3- has change from smallest to largest in anion which becoming the main anion in the groundwater on 2008 and 2009. Coefficient of variation of Ca2+、Mg2+、HCO3- had few change and kept in a stable content in the groundwater. In addition, coefficient of variation of Na+、Cl-、SO42- had a large change in the groundwater. As a result, Na+、Cl-、SO42- became a susceptibility factor varying with environmental factors and major variables that determined in groundwater salinization effect. The main chemical types of ground water were HCO3-Na (middle and lower reaches), SO4-Na (downstream) and Cl-Na (upstream) in irrigation district. Moreover, compared with the 2007, the concentration of HCO3- was increasing, but the concentration of Cl- and Na+ were decreasing. The groundwater was changing to more desalt water and small harm for crop. There was a complex spatiotemporal variation of chemical types for ground water. To follow the direction of groundwater flow, the chemical types of groundwater had been changed from Na-Ca-Mg-Cl-SO4-HCO3, Na-Mg-Cl-SO4-HCO3 and Na-Mg-Ca-HCO3- SO4-Cl to Na-Cl-SO4, Na-SO4-HCO3 and Na-Mg-Cl-HCO3. Furthermore, the chemical types of groundwater had been changed from Ca-Na-Mg-HCO3-SO4-Cl, Na-Mg-Ca-HCO3-SO4-Cl and Na-Mg-Cl-HCO3-SO4 to Na-Cl-HCO3-SO4, Na-HCO3-Cl-SO4 and Na-Ca-HCO3-SO4-Cl in 2008. In 2009 the chemical types of groundwater had been changed from Na-Ca-Cl-SO4-HCO3, Na-Mg-Ca-HCO3-SO4-Cl and Na-Mg-Ca-Cl-HCO3- SO4 to Na-HCO3-Cl-SO4, Na-Cl-SO4 and Na-Ca-Mg-Cl-SO4-HCO3. The Na+ had absolute predominance trend. Therefore, in chemical type aspect, HCO3- of anion in 2008 and 2009 was more primary chemical type than HCO3- of anion in 2007. The research results can give the references to evaluate the impacts of the water-saving upgrading program on water environment of regional soil.

       

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