Br离子液体中微波辐射加热促进稻草秸秆酸水解制备还原糖

    Microwave irradiation promoting acid hydrolysis of straw pole into reducing sugar in ionic liquid Br

    • 摘要: 为了探讨微波辐射及离子液体对酸催化植物纤维素水解的促进作用, 以稻草秸秆为原料,在BmimBr离子液体介质中,用微波辐射加热促进纤维素的酸水解,并对水解产物中的还原糖进行了测定。着重考察了微波辐射功率、微波辐射时间、硫酸浓度、反应温度等因素对还原糖收率的影响。结果表明,在BmimBr离子液体介质中,用微波辐射加热促进稻草酸水解制备还原糖的最佳条件是:30.0 mL质量分数为10.0%的硫酸、BmimBr10.0 mL、微波辐射温度85℃、微波辐射时间45 min、微波辐射功率500 W,在此条件下还原糖的收率达到了22.94%,而常规酸水解得到的还原糖收率为14.50%。显然,在BmimBr离子液体介质中,微波辐射加热促进稻草酸水解所得还原糖收率大于常规酸水解的所得还原糖收率。由此可知,离子液体介质中,微波辐射加热能够促进植物纤维素的酸水解,并显著缩短糖化时间,使得还原糖的收率提高。

       

      Abstract: In order to study the enhancement of acid hydrolysis process of plant fiber in BmimBr ionic liquid medium by the microwave irradiation heating, the microwave irradiation promoting acid hydrolysis of straw pole and preparation the reducing sugar were determined with the BmimBr ionic liquid as reactive medium in this paper. The influences of ionic liquid volume, microwave power, irradiation time, sulfuric acid concentration, reaction temperature on yield of reducing sugar with acid hydrolysis of straw pole were mainly tested. The results indicated that the best condition of acid hydrolysis of straw pole into reducing sugar in microwave irradiating was 10.0% H2SO430.0 mL, BmimBr 10.0 mL, reactive temperature 85℃, irradiation time 45 min, microwave power 500 W, and the yield ratio of reducing sugar reached 22.94% at the best condition, but the yield ratio of reducing sugar at the conventional acid hydrolysis was only 14.50%. It is clear that the yield ratio of reducing sugar in the straw pole by microwave irradiation promoting acid hydrolysis was higher than the yield ratio of reducing sugar by the conventional acid hydrolysis. So the microwave radiation could promote acid hydrolysis of plant fiber and significantly shorten the time of saccharification and raise the yield ratio of reducing sugar in the ionic liquid medium.

       

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