秸秆生物碳质吸附剂的制备及其吸附性能

    Preparation of biochar adsorbent from straw and its adsorption capability

    • 摘要: 为了开辟一条废弃生物质材料利用的新途径,该研究以小麦秸秆为生物质材料,通过中低温区间限氧升温熔融碳化方法制备生物碳质吸附剂,并以铜离子为例,研究吸附剂对废水中重金属的吸附性能。结果表明:在中低温区间(200~500℃)制备的吸附剂产率高、能耗小、制备工艺简单、吸附速率快、达到平衡时间短,最慢的吸附剂(P200)需要3 h达到吸附平衡,最快的吸附剂(P500)仅需0.5 h就达到吸附平衡。30℃时吸附剂P500对铜离子的饱和吸附量为11.19 mg/g。吸附动力学过程符合Lagergren准二级反应动力学模型,吸附等温线符合Langmuir方程,分离因子RL值在0~1之间,为有利吸附。扫描电镜分析显示,随着碳化温度的升高,秸秆的微孔变形程度加剧,增大了表面粗糙程度,孔道效应更易发挥,从而提高吸附性能,为生物质吸附剂的工程应用提供参考。

       

      Abstract: In order to find a new way of using discarded biomass materials, the wheat straw was used to prepare biochar adsorbent by means of carbonization at low and middle temperatures. Then, the Cu2+ was taken as adsorbed substance to investigate the biochar adsorbent adsorption capability for heavy metal from the wastewater. The results showed that the biochar adsorbent prepared at low and middle temperatures (200-500℃) obtained higher productivity with less energy consumption, easier process, higher adsorption speed and short time to reach the adsorption equilibrium. At the same time, it was found that the longest time to reach the adsorption equilibrium was 3 h (P200), and the shortest time was just only 0.5 h (P500). The maximum adsorption capacity of P500 could reach to 11.19 mg/g at 30℃. The adsorption kinetic process was consistent with the Lagergren pseudo-second order kinetic model. The adsorption isotherm agreed well with the Langmuir formulae, and the separation factor (RL) located in the range of 0-1 for favored adsorption. The SEM results indicated that the pore deformation and the straw roughness increased as the carbonization temperature rising, which made the pore canal effect easier and the adsorption properties more excellent. The research can provide a reference for engineering application of biomass adsorbent.

       

    /

    返回文章
    返回