稻壳热解模型建立与应用

    Model construction and application for rice husk pyrolysis

    • 摘要: 生物质连续热解工艺是适合工业化生产的高效、合理的处理方式,该文基于稻壳在升温速率为20~40?℃/min,反应终温为800℃的热分析试验数据,建立了稻壳热解过程的分段反应模型并获得了反应动力学参数,其中失水预热解阶段满足N阶反应,主热解阶段满足J-M-A方程。对所建模型在建模升温速率范围内、外进行了检验,发现模型计算结果与试验数据相近,模型计算误差不大于2.35%,说明模型具有较广泛的适用性,为热解反应器的设计提供了理论依据。根据稻壳常规热解下失水预热解和主热解反应过程的模型计算结果,设计了变螺距生物质连续热解反应器,并以稻壳粉末为原料进行了参数试验,结果表明,该反应装置能实现连续、稳定热解,但由于实际升温不是理论上的线性升温过程,导致连续热解试验结果与模型计算结果和热重试验结果间存在一定差异。

       

      Abstract: The process of biomass continuous pyrolysis is efficient and suitable for industrialization. In the paper, the rice husk pyrolysis model was built and kinetics parameters were obtained based on thermo analysis data of rice husk pyrolyzed at heating rate range from 20 to 40℃/min and final temperature of 800℃. Three stages were included in the process of rice husk pyrolysis: waterloss and pre-pyrolysis, main pyrolysis and carbonization. The stages of waterloss and pre-pyrolysis and main pyrolysis were calculated by the piecewise model. The result showed that the process of waterloss and pre-pyrolys accorded with N-step reaction, while main pyrolysis stage accorded with J-M-A equation. The pyrolysis model was tested in and out of the heating rate range which was used for model building. The verification result showed that the model calculated data was close to the experiment data, the error of the calcuated data was less than 2.35%. So it demonstrated that the pyrolysis model has a wide adaptability, which can provide a theoretical foundation for the design of pyrolysis reactor. A continuous biomass pyrolysis reactor with variable screw pitch had been designed and manufactured based on the model. The rice husk powder pyrolysis on the reactor was studied and it showed that the reactor could run continuously and stably. However, with different calefactive process, the char yields obtained in continuous pyrolysis experiment was lightly different from the calculated and thermo analysis result.

       

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