聚丙烯酸接枝碱木质素基铁肥的制备及其缓释性能

    Preparation and release performance of polyacrylic acid grafted alkali lignin-based iron fertilizer

    • 摘要: 为提高铁元素的累积释放率,以丙烯酸单体接枝无定形高分子碱木质素制备了具有保水、缓释功能的聚丙烯酸接枝碱木质素基铁肥(简写,ALS-G-P(AA)铁肥)。考察了丙烯酸中和度、引发剂用量、交联剂用量、温度、碱木质素接枝率等因素对ALS-G-P(AA)铁肥吸水倍率的影响,研究了ALS-G-P(AA)铁肥在水中的Fe离子的缓释行为。结果表明:最佳制备条件为丙烯酸中和度60%、引发剂用量0.06 g、交联剂用量0.03 g、温度为60℃、碱木质素接枝率为25%;该产物铁质量分数为7.74 mg/g,吸水倍率可达1 017 g/g。吸水饱和的ALS-G-P(AA)铁肥的肥效期为22 d,其在水中铁元素累积溶出特征符合一元二次方程模型,铁元素释放曲线呈"S"形。该研究为高效施用铁肥和碱木质素在农业可降解缓/控释载体领域的应用提供了参考,并有望进一步拓展。

       

      Abstract: To improve the cumulative release rate of iron, polyacrylic acid grafted alkali lignin-based (ALS-G-P (AA)) iron fertilizer was prepared by acrylic monomer grafted the amorphous alkali lignin. The influences on water absorbency of the materials to neutralization degree of acrylic acid, the dosage of initiator and cross-linking agent, temperature and grafting degree of alkali-lignin were investigated by orthogonal test. Release performance of ALS-G-P (AA) iron fertilizer was researched. The results showed the ideal preparation conditions were as follow: the degree of acrylic acid was 60%, amount of initiator was 0.06 g and the cross-linking agent was 0.03 g, temperature was 60℃ and alkali-lignin grafting was 25%. Water absorbency of ALS-G-P (AA) iron fertilizer was 1 017 g/g, the iron content of which was 7.74 mg/g. Effective release period of water saturated ALS-G-P (AA) iron fertilizer with was 22 days. Iron cumulative released rate of ALS-G-P (AA) iron fertilizer in water fitted a quadric equation. Curve of the iron cumulative release rate was S pattern. The study provides a reference for the efficient application of iron fertilizer, and expanded application of the alkali lignin in agricultural fields of controlled release carriers.

       

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