周吓星, 陈礼辉, 林巧佳. 竹粉/聚丙烯发泡复合材料的增韧效果[J]. 农业工程学报, 2013, 29(2): 266-272.
    引用本文: 周吓星, 陈礼辉, 林巧佳. 竹粉/聚丙烯发泡复合材料的增韧效果[J]. 农业工程学报, 2013, 29(2): 266-272.
    Zhou Xiaxing, Chen Lihui, Lin Qiaojia. Toughening effect of bamboo flour /polypropylene foamed composite[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2013, 29(2): 266-272.
    Citation: Zhou Xiaxing, Chen Lihui, Lin Qiaojia. Toughening effect of bamboo flour /polypropylene foamed composite[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2013, 29(2): 266-272.

    竹粉/聚丙烯发泡复合材料的增韧效果

    Toughening effect of bamboo flour /polypropylene foamed composite

    • 摘要: 为研发可代替聚丙烯(polypropylene,PP)应用于汽车内饰件的木塑复合材料,减少白色污染,节约化石能源,同时提高木塑复合材料的附加值,拓宽其应用领域。该文以注塑法制备竹粉/聚丙烯发泡复合材料,并分别采用乙烯-1-辛烯共聚物(polyolefin elastomer,POE)和马来酸酐接枝POE(maleic anhydride grafted polyolefin elastomer,POE-g-MAH)增韧复合材料。研究了增韧填料对发泡复合材料力学性能的影响,用环境扫描电镜(environmental scanning electronic microscopy,ESEM)对复合材料的冲击断面进行观察,并进行了频率扫描的动态流变测试。结果表明:添加POE和POE-g-MAH在略微降低材料拉伸和弯曲强度的同时,可明显提高材料的缺口冲击强度,二者最佳用量分别为15%和8%;8%POE-g-MAH增韧的复合材料的缺口冲击强度为8.55 kJ/m2,提高了35.7%,可很好地应用于汽车内饰件。ESEM显示,增韧后,复合材料的断裂形式转变为韧性断裂。动态频率扫描结果显示,POE对复合材料流变性能的影响较小,而POE-g-MAH增韧的复合材料的储能模量和复数黏度明显增大,且"第二平台"现象更为明显。

       

      Abstract: Abstract: In order to make full use of bamboo resources in China and reduce white pollution, save fossil energy, the foamed composite of 54 wt% PP and 13 wt% HMSPP containing 33 wt% bamboo powder and 1% modified azodicarbonamide (AC) foaming agent blends was prepared by injection molding. Meanwhile, in order to substitute for polypropylene(PP) applied to automotive interior parts and thus broaden the application fields of wood-plastic composite, the bamboo powder/polypropylene foamed composites toughened by polyethylene octane elastomer (POE) and maleic anhydride grafted polyolefin elastomer (POE-g-MAH) were researched. Effects of the two toughen fillers on mechanical properties including bending, tensile and impact strengths were studied and the impact fractured surfaces of non-toughened and toughened composites were investigated by environmental scanning electronic microscopy micrograph (ESEM). The rheological behavior of composites with respect to frequency sweep ranging from 0.01 Hz to 100 Hz at 180℃ was carried out. The results showed that the tensile and bending strengths were reduced slightly and notched impact strength of composites was improved significantly with the increase of toughen fillers content. The optimum amounts of POE and POE-g-MAH were 15% and 8% respectively. The tensile strength of 15% POE toughening composite was unable to meet the standard of automotive interior parts, although its notched impact strength was increased from 6.30 kJ/m2 to 7.65 kJ/m2. The 8% POE-g-MAH toughening composite could well be applied to automotive interior parts and its bending strength, bending modulus and tensile strength of 37.5 MPa, 2.69 GPa and 21.02 MPa respectively, which was reduced by 1.2%~6.9%, while the notched impact strength was 8.55 kJ/m2, which was increased by 35.7% compared with the non-toughened composite. ESEM observation of the impact fracture morphology indicated that the fracture mode of toughened composite transited into ductile fracture. The frequency sweep results showed that the effect of POE on the rheological behavior was relatively smaller than that of POE-g-MAH. The storage modulus and complex viscosity of composite toughened by POE-g-MAH were increased and the "second platform" phenomenon was more evident.

       

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